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The δ 18OVSMOW values of Katian conodonts fluctuate around 18.9‰.
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There is no evidence of cooling or glaciation during the sampled ~ 5.7 m.y..
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Temperatures remained relatively constant throughout most of the Katian.
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Glaciation began either prior to the Katian or during the Hirnantian.
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Statistically significant offset exits in δ 18O for the conodont taxa analyzed.
Abstract
The major glaciation at the end of the Ordovician is associated with
the 2nd largest mass extinction event of the Phanerozoic. Growth of Late
Ordovician ice sheets requires a dramatic cooling from the ‘greenhouse’
conditions that prevailed for most of the Ordovician, but when and how
fast this cooling occurred is controversial. The controversy is due
in large part to a lack of good geochemical constraints on the
temperature history of the Katian (453–445.2 Ma). To address this
uncertainty, we measured phosphate δ18O
values from 3 conodont species collected from sections in the
midcontinent region of the United States that span an ~ 5.7 m.y. long
interval covering most of the Katian. Results reveal a statistically
significant offset in δ18O
values between some taxa and show up to 2‰ differences among samples.
However, there are no apparent long-term trends within or between
sections; rather, values fluctuate around a δ 18O
mean of ~ 19‰ VSMOW. Our study provides the longest, relatively high
resolution, species specific conodont record generated for this
interval, and we found no evidence supporting progressive cooling during
the Katian.
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